; Chance, R.R. wide variety of materials for applications as primary solid state explosives and detonating agents. Molar Mass: 184.2868 Thus formation of tetrasulfur tetranitride would involve the combination reaction $\ce{4 S^{IV} +4 N^{-III} -> S4N4}$ But we see that to balance charges four electrons must be added, so sulfur tetranitride is actually a reduction : Dates: Modify . Predicted data is generated using the US Environmental Protection Agency’s EPISuite™. The compound was first reported as early as 1910 by F.P. Highlight all Match case. ; [12], The material is a polymer. …two most interesting ones are tetrasulfur tetranitride, S4N4, and disulfur dinitride, S2N2, because they are precursors to an unusual polymer called polythiazyl, (SN)x. Main Content. Element analysis. ; Russo, P.J. In accordance with the name of the journal, which means “Journal for Natural Sciences”, manuscripts submitted to ZNA should have a tangible connection to actual physical phenomena. S4N4 adopts an unusual “extreme cradle” structure, with D2d point group symmetry. Other articles where Tetrasulfur tetranitride is discussed: nitride: Sulfur nitrides: …two most interesting ones are tetrasulfur tetranitride, S4N4, and disulfur dinitride, S2N2, because they are precursors to an unusual polymer called polythiazyl, (SN)x. : MacDiarmid, A.G.; Mikulski, C.M. : Novel chemistry and applications of polythiazyl, Doctoral Thesis Loughborough University 2009, pdf-Download, Except where otherwise noted, data are given for materials in their. [18], King, R.S.P. [2][1][18], Due to its electrical conductivity, polythiazyl is used in LEDs, transistors, battery cathodes, and solar cells. We assume you are converting between moles Tetrasulfur Tetranitride and gram. Tetrasulfur Tetranitride S4N4 Molar Mass, Molecular Weight. [2][13][14] Several resonance structures can be written. tetrasulfur tetranitride; The oxidation number of sulfur in tetrasulphur tetranitride is 3. Tetranitrogen tetrasulfide. Meaning of tetrasulphur tetranitride. A Journal of Physical Sciences: Zeitschrift für Naturforschung A (ZNA) is an international scientific journal which publishes original research papers from all areas of experimental and theoretical physics. However, the relatively low transition temperature at about 0.3 K makes a practical application unlikely. S bonds in S 4 N 4 are broken and the molecule assumes an open, monocyclic conformation. This polymeric sulfur nitride is unusual because, even though it is composed solely of two nonmetals, it exhibits … Afterwards, dry NH 3 was introduced into the three-necked flask at a flow rate of 1200 mL min −1. [9][10] At temperatures above 240 °C explosive decomposition can occur. ; Heeger, A.J. The monoclinic form I obtained from the synthesis can be converted into an orthorhombic form II by mechanical treatment such as grinding. Definition of tetrasulphur tetranitride in the Definitions.net dictionary. However, the relatively low transition temperature at about 0.3 K makes a practical application unlikely. (1). The compound was the first non-metallic compound in which superconductivity could be demonstrated. ; Saran, M.S. tetrasulfur tetranitride (uncountable) ( inorganic chemistry ) a simple binary compound of sulfur and nitrogen , S 4 N 4 , having a ring structure; it is explosive Related terms [ edit ] ; Garito, A.F. [16][17][9][8], Polythiazyl is synthesized by the polymerization of the dimer disulfur dinitride (S2N2), which is in turn synthesized from the cyclic alternating tetramer tetrasulfur tetranitride (S4N4). It is a gold solid. The mass (in grams) of a compound is equal to its molarity (in moles) multiply its molar mass: grams = mole × molar mass. It can be viewed as a derivative of a hypothetical eight-membered ring of alternating sulfur and nitrogen atoms. Find out what is the full meaning of TETRASULFUR TETRANITRIDE on Abbreviations.com! This showed alternating SN bond lengths of 159 pm and 163 pm and SNS bond angles of 120 °C and NSN bond angles of 106 °C. Furthermore, because elemental sulfur has been an item of commerce for centuries, its various forms are given traditional names. Along the fibres or SN chains, the bond is electrically conductive, perpendicular to it acts as an insulator. It is air stable and insoluble in all solvents. 1970. Tetrasulfur tetranitride, also known as tetrasulphur tetranitride, is a chemical compound. The pairs of sulfur atoms across the ring are further bonded, resulting in a cage-like structure with pentagonal S3N2 rings. Author(s): Lipp, Steven A. Jolly, William L. et al.... Main Content Metrics Author & Article Info. [8], Two polymorphic crystal forms were observed in the compound. 1 Structures Expand this section. Tetrasulfur tetranitride is prepared by dissolving 1 volume of sulfur dichloride in 8 or 10 volumes of carbon disulfide, cooling, and passing in dry ammonia gas until the dark brown powdery pre­cipitate which forms at first has dissolved and an orange-yellow solution results which contains light-colored flocks of ammonium chloride. : Baughman, R.H.; Apgar, P.A. You can view more details on each measurement unit: molecular weight of Tetrasulfur Tetranitride or grams The molecular formula for Tetrasulfur Tetranitride is S4N4. Information and translations of tetrasulfur tetranitride in the most comprehensive dictionary definitions resource on the web. A QTAIM and stress tensor perspective of large-amplitude motions of the tetrasulfur tetranitride S 4 N 4 molecular graph. Tetrasulfur tetranitride and tellurium tetrachloride react in dichloromethane to form a 1:1 adduct (TeCl4S4N4)-S-. Looking for the definition of TETRASULFUR TETRANITRIDE? tetrasulfur tetranitride, S4N4, and disulfur dinitride, S2N2, because they are precursors to an unusual polymer called polythiazyl, (SN)x. [10], Polythiazyl shows an anisotropic electrical conductivity. : https://en.wikipedia.org/w/index.php?title=Polythiazyl&oldid=977982896, Chemicals that do not have a ChemSpider ID assigned, Articles containing unverified chemical infoboxes, Creative Commons Attribution-ShareAlike License, This page was last edited on 12 September 2020, at 04:44. Carlo A. Ghilardi, Stefano Midollini, Simonetta Moneti and Annabella Orlandini, Reactivity of tetrasulfur tetranitride towards d10 phosphine complexes. Polythiazyl (polymeric sulfur nitride), (SN)x, is an electrically conductive, gold- or bronze-colored polymer with metallic luster. Synthesis of tetrasulfur tetranitride (S 4 N 4) CCl 4 (250 mL) and S 2 Cl 2 (40 mL, 0.5 mol) were added to a 500 mL three-necked flask at 0 °C with stirring. The table shows element percentages for S 4 N 4 (tetrasulphur tetranitride). This polymeric sulfur nitride is unusual because, even though it is composed solely of two nonmetals, it exhibits some properties normally associated only with metals. Contents. More... Molecular Weight: 184.3 g/mol. The Web's largest and most authoritative acronyms and abbreviations resource. (tetrasulfur tetranitride, a pale yellow to orange inorganic compound with the formula of S 4 N 4, is used to synthesize nitrogen heterocycles IR 928, … Burt, who obtained it by heating tetrasulfur tetranitride in vacuum over silver wool. 2020-12-12. 9BXS997HR6. [3][4] It is a fibrous solid, described as "lustrous golden on the faces and dark blue-black", depending on the orientation of the sample. The best…. 3 Chemical and Physical Properties Expand this section. Definition of tetrasulfur tetranitride in the Definitions.net dictionary. [15], The structure of the crystalline compound was resolved by X-ray diffraction. part i. ; the reaction of tetrasulfur tet-ranitride with sulfuric acid. International Journal of Quantum Chemistry 2016 , 116 (13) , 1025-1039. : MacDiarmid, A.G.; Mikulski, C.M. Whole words. The element sulfur exists as many allotropes.In terms of large number of allotropes, sulfur is second only to carbon. It was the first conductive inorganic polymer discovered[1][2] and was also found to be a superconductor at very low temperatures (below 0.26 K). Synthesis. Properties. [11] The compound also explodes on impact. Element % N: 30.40: S: 69.60: Isotope pattern for S 4 N 4. The one-dimensional conductivity is based on the bonding conditions in the S-N chain, where each sulfur atom provides two π electrons and each nitrogen atom provides one π electron to form two-center 3π electron bonding units. Crystal structure of (PPh3)Pt(μ-S2N2)2Pt(PPh3) , Journal of Organometallic Chemistry , 286 , 3 , (419) , (1985) . The S and N atoms on adjacent chains align. Heeger, A.J. ; Meyer, H.-J. Representative compounds include tetranitrogen tetrasulfide, $4N4; tetrasulfur dinitride, S4N2 … Thumbnails Document Outline Attachments. The chemistry of sulfur-nitrogen compounds has several features of interest and importance: stability of the sulfur-nitrogen bond, tendency to form six- and eight-membered rings, ring contraction, polymerization, and negative ion formation. The bonding in S4N4is c… ; Russo, P.J. Previous. Such long absence of interests in NTz-based materials, despite its promising feature as discussed above, can be due to the lack of suitable synthetic methods of NTz framework itself. Download PDF to View View Larger. The nature of the "transannular" S-S interactions is a matter of debate and computational investigation but has been explained in the context of molecular orbital theory. Polarographic waves for tetrasulfur tetranitride (2.5 mM) at 25 'C. E1/2 = -0.380 V and E1/2 = -0.670 V. the wave occurring at E1/2 = -0.890 V were consis- tently larger then those of the other two waves by a factor of ten; whereas the diffusion currents of the waves at E/2 = -0.380 V and E1l2 = -0.670 V were approximately the same. ; Cohen, M.J.; Bright, A.A.; Garito, A.F. THE REACTION OF TETRASULFUR TETRANITRIDE WITH SULFURIC ACID. 28950-34-7. As shown in Scheme 1, the NTz framework was constructed by a reaction of naphthalene dioles with tetrasulfur tetranitride (N 4 S 4) as the key step. [5], The compound was first reported as early as 1910 by F.P. These materials are available in solid, liquid, and plastic forms. part ii Alsfasser, R.; Janiak, C.; Klapötke, T.M. Afterwards, dry NH 3 was introduced into the three-necked flask at a flow rate of 1200 mL min −1. By signing up for this email, you are agreeing to news, offers, and information from Encyclopaedia Britannica. What does tetrasulfur tetranitride mean? Tetrasulfur tetranitride. https://www.britannica.com/science/tetrasulfur-tetranitride. Synthesis of tetrasulfur tetranitride (S 4 N 4) CCl 4 (250 mL) and S 2 Cl 2 (40 mL, 0.5 mol) were added to a 500 mL three-necked flask at 0 °C with stirring. Create . epr studies of tetrasulfur tetranitride in sulfuric acid. In addition to the allotropes, each allotrope often exists in polymorphs, delineated by Greek prefixes (α, β, etc.).. The SI base unit for amount of substance is the mole. ; Saran, M.S. The mass and molarity of chemical compounds can be calculated based on the molar mass of the compound. [6], The compound was the first non-metallic compound in which superconductivity could be demonstrated. Next. What does tetrasulphur tetranitride mean? Because of their chemical inertness and ability to withstand high temperatures, interstitial nitrides are useful in several high-temperature applications, including their use as … ; MacDiarmid, A.G.; Garito, A.F. 2005-03-27. It is composed of the elements sulfur (S) and nitrogen (N) with a weight of 184.3 grams per mole. Log Octanol-Water Partition Coef (SRC): Log Kow (KOWWIN v1.67 estimate) = 2.63 Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPWIN v1.42): Boiling Pt (deg C): 655.53 (Adapted Stein & Brown method) Melting Pt (deg C): 285.25 (Mean or Weighted MP) VP(mm Hg,25 deg C): 3.34E-015 (Modified Grain … Disulfur tetranitride is the chemical name of the molecular formula S4N4. Information and translations of tetrasulphur tetranitride in the most comprehensive dictionary definitions resource on the web. It contains sulfur in its +3 oxidation state. Burt, who obtained it by heating tetrasulfur tetranitride in vacuum over silver wool. Its chemical formula is S 4 N 4. Meaning of tetrasulfur tetranitride. [8] The polymer is mostly inert to oxygen and water, but decomposes in air to a grey powder. Not available. UNII-9BXS997HR6. It also contains nitride ions. [2] Conversion from cyclic tetramer to dimer is catalysed with hot silver wool. [7][8], Polythiazyl is a metallic-golden and shiny, crystalline but fibrous material. 2 Names and Identifiers Expand this section. Be on the lookout for your Britannica newsletter to get trusted stories delivered right to your inbox. Temperature at about 0.3 applications of tetrasulfur tetranitride makes a practical application unlikely for S 4 N 4 forms were observed the. Newsletter to get trusted stories delivered right to your inbox bronze-colored polymer with metallic.! Klapötke, T.M be calculated based on the molar mass of the compound was the first non-metallic compound in superconductivity! 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